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If you make a payment directly to a supplier, you can record this using an expense in QuickBooks.
If adding the payment directly from a connected bank feed in QuickBooks, you can add this as an expense or as a payment on account.
To add as a payment on account from the bank transaction For review feed, change the Account to Creditors when reviewing the payment details. Once added, the payment will show on the suppliers account and can be added to any future bill as payment.
Note, if you have already added the transaction as an expense from the bank feed and want to change this, you can undo the transaction by going to Transactions > Bank transactions > Categorised > Select undo beside the transaction. This will move it back to the For review feed where it can be reviewed again.