Hello,
QBO can only import information that your bank feeds it. Most banks when you look at the transactions on their website dont list a Payee. Only date, amount, and description.
What you CAN do though, is if you know the payee is always the same based on a word in the description, you can create a rule that QBO automatically adds the payee when it downloads the transaction.
Ex:
If Description has the word "Homedepot" assign Payee "Home Depot"