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Yes, you can add a second bank account directly from your Chart of Accounts. Let me show you how.
But if you're meaning to add a second bank account for your payroll payments account, doing so is not possible.
Additionally, you can also browse for the content of this reference for a compilation of banking topics you can use in the future: QuickBooks Online Banking.
If you have any other questions or if you're referring to something else, please let me know in the comments below. Stay safe!