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We are only able to customize certain fields in your invoice template, adding a new column is currently unavailable. You can read through this article to learn more: Customize invoices, estimates, and sales receipts in QuickBooks Online.
With this, you can consider utilizing one of our integrated apps from the app center so you can fully customize your invoice template:
Lastly, here's an article you can read to learn more about how you can start creating an invoice: Create invoices in QuickBooks Online.
Keep me updated in the comments if you have any other questions. I'll be here to lend a hand,
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