Hello Jennyandinchristi
When it comes to paying off your invoice and their bill you will need to use a journal entry
You can go to the plus symbol and then journal entry to create this.
It is a case of creating 2 lines one to debtors and the amount(under the credits side) with the customer name selected and then the other to creditors and the amount(under the debit side) selecting the supplier name on that line
You can then go to the invoice and select receive payment and use the journal and the same on the supplier and make a payment on the bill
If you need to enter differing amounts the other option would be doing two separate journals and using a contra account which we can go through as an alternative
Let us know how you get on
Thanks
Emma