Hi, @wsenti0.
Welcome back to the Community. For me to better assist you, is there a particular reason that you'd like two different payroll items for vacation hours? If it's for accounting purposes, then you'll need to change the payroll settings to have it track differently for each employee. Here's how:
That's it! Here's an extra link that might be helpful to you in the future: set up and pay sick and vacation time.
Remember, I'm only a comment away if you need me. Have a wonderful day!