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I'm glad to see you here in the Community, @orbiteers1.
The option to add the pay now button to statements is currently unavailable. You can only enable it to invoices. To do so, you have to link your Payments account to QuickBooks. If you don't have one, you'll need to sign up for QuickBooks Online Payments.
Then, here's how to turn on and send online invoices:
For more info about this process, please see this link: Take and process payments in QuickBooks Online.
Also, to know when QuickBooks deposits customer payments into your bank account, you may check out our deposit times for the QuickBooks Payments page.
Feel free to leave a reply below if you have further concerns about online payments. I want to make sure you're taken care of, and I'm here to help you anytime. Take care always.